Using Muscle the Machop
Go to the top floor of the Goldenrod Department Store, where you'll find a man who wants to trade you his Machop, Muscle. He'll ask for Drowzee in Gold and Silver, and Abra in Crystal. Both can be found on Route 34, the route below Goldenrod City. Abra can also be bought from the Game Corner for 200 coins if you don't want to deal with it fleeing from a wild battle.
Level Muscle to at least level 18. Whitney's Miltank is level 20, so you'll want to level it up high enough to stand a chance against the Miltank.
Use its Low Kick and Karate Chop attacks against the Miltank. Given that those attacks are Fighting-type attacks, they'll be super effective. It'll also be resistant to Miltank's Rollout (a Rock-type attack).
Using an Accuracy-Lowering Strategy
Have a Pokémon with an attack that lowers accuracy such as Smokescreen or Sand-Attack. If you started with Cyndaquil, it'll learn Smokescreen while Pidgey can learn Sand-Attack. Both should be evolved to their second forms by the time you reach Whitney.
Use your accuracy-lowering attack against the Miltank. By lowering its accuracy, its attacks will miss more often, giving you a better chance of defeating it.
After using your accuracy-lowering attack against the Miltank a few times, attack it. Special attacks such as Thundershock or Ember will work better than physical attacks, given Miltank's lower special defense. You can buy Thunder Punch, Fire Punch, and Ice Punch in the Goldenrod Department Store if you have any Pokémon that can learn one or more of those attacks (Abra, in particular, can learn all three and has a high special attack).
Using a Curse Strategy
Capture a Gastly and have it learn Curse. Curse will cut down Gastly's HP in exchange for a curse that damages the opposing Pokémon every turn.
Use Curse against her Miltank. Stomp won't affect your Gastly, so if your Gastly is female, Miltank will have to resort to Rollout, which will be unlikely to KO your Gastly on the first turn.
Attack and/or status the Miltank while it's under the curse. Eventually, Miltank should go down to a combination of your attack damage and the damage from the curse.
Using a Status-Inflicting Strategy
Get a Pokémon with an attack that inflicts a status on the opposing Pokémon. By this point, you'll be able to inflict paralysis, poison, or sleep. If you started with Chikorita, it'll be able to learn Stun Spore and Poison Powder. Paralysis lowers a Pokémons' speed and has a 25% chance of stopping the Pokémon from making a move during a turn. Poison damages the opponent a bit at the end of their turn. Sleep makes the opponent fall asleep, preventing them from moving until they wake up.
Use your status-inflicting attack on the Miltank. Poison or paralysis is your best bet here, given that sleep isn't always reliable, but whichever you use is your preference.
Attack the Miltank while it's under the status you inflict on it.
Using a Rollout Strategy
Get the TM for Rollout, which is north of Goldenrod City on Route 35.
Teach it to a compatible Pokémon, which includes Geodude and Quilava.
Use Rollout on Clefairy. By the time Clefairy is KO'd, Rollout should have already gone for 3 or 4 turns, making it very powerful. When Miltank comes out, it'll be hit by Rollout, and (depending on your level) should do a good amount of damage against it, if not a one-hit KO. If it misses at any point, you get flinched by Miltank's Stomp attack, or your Pokémon is immobilized by love through Attract, though, Rollout will end, making this strategy dependent on luck.
Using a Wall Strategy
Catch a Geodude or Onix. Preferably, a female one, since a female one will be immune to Attract. You can trade a Bellsprout for Onix in Violet City, or catch one in Union Cave. Geodude can also be caught in Union Cave, along with Dark Cave and the bottom part of Route 46.
Use it against the Miltank. Both Geodude and Onix are Rock/Ground-types and have high defense, making them a good choice to use against Whitney.
Using a Rage Strategy
Choose Totodile as your starter Pokémon and have it learn Rage. Rage is an attack that increases your attack power when you're hit, as long as it's used consecutively. By the time you reach Whitney, Totodile should have evolved into Croconaw.
Use Rage against Clefairy. If you get lucky, Clefairy will use Double Slap and hit you 5 times with it, increasing your attack power with each hit. By the time it's KO'd and Miltank comes out, you should hopefully have enough attack power to do a good amount of damage against Miltank. If you use a different attack, though, the attack power will reset, so be sure that you're using it constantly.
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